Tin Transition metals

Figure 10.9 Some examples of metal sequences and metal clusters containing tin-transitional metal bonds.

The structural aspects of tin-transition metal complexes are well studied. Some recent examples of metal-tin single and double bonded complexes are provided in Tables 11 and 12. 

Table 19-5 Compounds with a tin-transition metal bond.

B. Divalent Organotin Compounds Containing a Tin-Transition Metal... 

Schente 2.1.10 Two examples of extreme nuclear magnetic deshielding in low valent tin transition metal complexes... 

The chemistry of silicon, germanium, and tin transition metal compounds has been the subject of several reviews (12, 180). Optically active silyl ligands have been introduced in a transition metal complex by reaction of chiral functional organosilanes. However chiral silyl ligands containing complexes are limited to a few metal centers we shall discuss in turn iron, cobalt, platinum, and manganese complexes. 

A number of organotin compounds with a tin-transition-metal bond have been examined this bond has usually been to iron to facilitate study... 

No systematic studies of other tin-transition metal systems have been reported. The existing data for a few compounds (12, 63) are insufficient to allow interpretation in terms of bonding or structure. 

Group IVB.—A survey of their reactions with electrophiles suggests that organo— tin-transition-metal complexes may be regarded as pseudohalides aliphatic C—Sn bonds are deactivated, and aromatic C—Sn bonds activated. Transition-... 

Many transitional metals have now been incorporated into compounds containing tin-transitional metal bonds io. 28s. xhe syntheses can be roughly divided into four main classes. 

The number of individual compounds that possess one or more tin-transitional metal bonds is very large, and the table only includes some representative examples. 

A number of reagents cause fission of the tin-transitional metal bond so. 29t. 

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