TICI3, Thallium chloride

T1C1F i2, Thalliuni(III), chlorobis(pen-tafluorophenyl)-, 21 71, 72 TICI3, Thallium chloride, 21 72 Tl2N4PtC4, Platinate(II), tetracyano-, dithallium, 21 153... 

Thallium(lll) chloride tetrahydrate TICI3-4H30 13463-32-2 382.804 orth cry 3.00 sH,0... 

Reactions of thallium(IIJ) ions To study these reactions use a 0.2m solution of thallium(III) chloride, TICI3. Note that all thallium salts are HIGHLY POISONOUS ... 

Thallium ( T1) (1= 1/2,1/2). The synthesis of thaUimnCIII) chloride and bromide was performed in solution by chlorination and bro-mination, respectively, of the suspensions of the corresponding thalhum(I) halides in acetonitrile. The T1 NMR study of thallium(III) chloride in dimethylsulfoxide showed three sep. signals assigned to the solvated TIQT, TICI3 and TlCli species. 

Thallium(III) exhibits coordination numbers higher than 4 in complex chlorides, prepared by addition of chloride salts to TICI3. In [H3N(CH2)5NH3][T1C15], a square-based pyramidal structure for the anion has been confirmed (Fig. 13.17a). In K3[TlCl6], the anion has the expected octahedral structure, and in CS3 [TI2CI9], the T1(III) centres in the anion are also octahedral (Fig. 13.17b). 

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