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Three-dimensional free quantum-rotor

Fig. 5.18 A three-dimensional free quantum-rotor model and possible nuclear spin-rotational state couplings (Vnt Va) for (a) CH3 and (b) CD3 radicals in the7>3 symmetry. The observed 1 1 1 1 queirtet and 2 2 doublet of CH3 are attributed to four A1 and two doubly degenerated E nuclear spin states coupled with rotational ground 7 = 0 (even) and excited 7=1 (odd) states, respectively. For CD3 only one A2 nuclear spin state is possible in the 7 = 0 state. B stands for the theoretictil rotational constant... Fig. 5.18 A three-dimensional free quantum-rotor model and possible nuclear spin-rotational state couplings (Vnt Va) for (a) CH3 and (b) CD3 radicals in the7>3 symmetry. The observed 1 1 1 1 queirtet and 2 2 doublet of CH3 are attributed to four A1 and two doubly degenerated E nuclear spin states coupled with rotational ground 7 = 0 (even) and excited 7=1 (odd) states, respectively. For CD3 only one A2 nuclear spin state is possible in the 7 = 0 state. B stands for the theoretictil rotational constant...
See other pages where Three-dimensional free quantum-rotor is mentioned: [Pg.239]    [Pg.240]    [Pg.258]    [Pg.239]    [Pg.240]    [Pg.258]    [Pg.97]    [Pg.432]   
See also in sourсe #XX -- [ Pg.239 , Pg.258 ]



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