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Three-centre bonds cluster anions

There are three important routes to the formation of the mercury-transition metal bond (a) displacement of halogen or pseudohalogen from mercury(II) salts with carbonyl metallate anions (b) reaction of a halo-phenylmercury compound with a transition metal hydride and (c) oxidative addition of a mercury halide to neutral zero valent metals.1 We report here the syntheses of three compounds containing three-centre, two-electron, mercury-ruthenium bonds utilizing trinuclear cluster anions and mercury(II) halides.2-4... [Pg.329]


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See also in sourсe #XX -- [ Pg.374 , Pg.393 ]




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Bonding three-centre

Centres anionic

Cluster anionic

Cluster anions

Clusters bonding

Three-centre bonds

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