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Thioxanthate complexes

Differences in E% values between thioxanthate complexes and dithioacid complexes for equivalent processes have been related to the superior electron-... [Pg.352]

The spectra of the thioxanthate complexes (351) are qualitatively similar to those observed for the dithioacid derivatives (520), where efficient mixing of ligand 77 and the metal dx orbital has been suggested to account for the absence of transitions of pure d-d origin. [Pg.352]

Carbon disulfide elimination (Eq. 55) appears to be a general reaction of the thioxanthate complexes (153). [Pg.449]

Insertion of carbon disulfide into M-H, M-C and M-S bonds is a well-known process (see GOMG (1995)). In accord, thiolato complex [Ru(SGH2GH=GH2)Gp(PPh3)2] readily reacts with GS2 to give the thioxanthate complex... [Pg.493]


See other pages where Thioxanthate complexes is mentioned: [Pg.223]    [Pg.242]    [Pg.256]    [Pg.298]    [Pg.1354]    [Pg.173]    [Pg.350]    [Pg.351]    [Pg.407]    [Pg.435]    [Pg.1246]    [Pg.1991]    [Pg.223]    [Pg.242]    [Pg.256]    [Pg.1990]    [Pg.435]    [Pg.1246]    [Pg.3193]    [Pg.3889]    [Pg.4700]    [Pg.5046]    [Pg.242]   
See also in sourсe #XX -- [ Pg.407 ]




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