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Thiophene copolymers with oxadiazole moieties in the main chain

5 Thiophene copolymers with oxadiazole moieties in the main chain [Pg.725]

Only a few thiophene copolymers with electron-deficient 1,3,4-oxadiazole units are known. Huang and co-workers synthesized copolymers 84 and 85 and demonstrated that structural variations, particularly different lengths of the oligothiophene fragments, allowed tuning of the bandgap and PL energy of these materials = 489 nm 530 nm 580 nm (84 a b c), 462 nm (498, 526 nm) 568 nm [Pg.725]




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1,2,3-Oxadiazol

1,2,4-Oxadiazole

Chain copolymers

In copolymers

Main-chain

Oxadiazole-thiophene copolymers

Thiophene copolymers

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