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Thionitrosyl complexes structures

Thiazyl monomer can be stabilized by coordination to a metal, and many thionitrosyl complexes with Cr, Mo, Re, Ru, Os, Co, Rh, Ir, and Ft are known.Comparison of the spectroscopic properties and the electronic structures of M-NS and M-NO complexes indicates that NS is a better a-donor and r-acceptor ligand than NO. Oxygen transfer from an NO2 to an NS ligand on the same metal center occurs in ruthenium porphyrin complexes. ... [Pg.4647]

Thionitrosyl compounds are less common, but the few structurally characterized representatives suggest a close similarity to the chemistry of nitrosyl complexes. [Pg.363]


See other pages where Thionitrosyl complexes structures is mentioned: [Pg.81]    [Pg.722]    [Pg.51]    [Pg.60]    [Pg.226]    [Pg.238]    [Pg.367]    [Pg.1395]    [Pg.120]    [Pg.120]    [Pg.799]    [Pg.204]    [Pg.553]    [Pg.73]    [Pg.4081]    [Pg.73]    [Pg.161]    [Pg.171]    [Pg.172]    [Pg.722]    [Pg.283]    [Pg.309]    [Pg.48]    [Pg.57]    [Pg.4080]    [Pg.204]    [Pg.553]    [Pg.766]    [Pg.766]    [Pg.766]    [Pg.1445]    [Pg.3234]    [Pg.3658]    [Pg.4007]    [Pg.14]    [Pg.185]    [Pg.235]    [Pg.652]    [Pg.259]    [Pg.1290]    [Pg.471]    [Pg.249]    [Pg.1087]    [Pg.118]    [Pg.300]    [Pg.4]    [Pg.2168]    [Pg.4]    [Pg.503]   
See also in sourсe #XX -- [ Pg.2 , Pg.120 ]




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