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Thionitrosyl complexes bonding

The nitrogen atom in the (almost) linear metal-thionitrosyl complexes is 5p-hybridized and the NS ligand behaves as a three-electron donor. The N-S bond distances in metal complexes vary between 1.45... [Pg.124]

Two bonding modes, linear and bent, have been established for metal-thionitrosyl complexes. The characteristic stretching vibration for linear M-NS complexes occurs in the range 1150-1370cm , while that for terminal bent complexes appears at lower frequencies. [Pg.4648]


See other pages where Thionitrosyl complexes bonding is mentioned: [Pg.81]    [Pg.234]    [Pg.51]    [Pg.238]    [Pg.163]    [Pg.832]    [Pg.997]    [Pg.120]    [Pg.122]    [Pg.1100]    [Pg.117]    [Pg.566]    [Pg.73]    [Pg.73]    [Pg.161]    [Pg.283]    [Pg.309]    [Pg.48]    [Pg.566]    [Pg.766]    [Pg.766]    [Pg.768]    [Pg.1746]    [Pg.2671]    [Pg.2836]    [Pg.4020]    [Pg.14]    [Pg.263]    [Pg.504]    [Pg.280]    [Pg.156]    [Pg.122]    [Pg.124]    [Pg.190]    [Pg.185]    [Pg.268]    [Pg.235]    [Pg.325]    [Pg.366]    [Pg.366]    [Pg.367]    [Pg.652]    [Pg.156]    [Pg.156]    [Pg.249]   
See also in sourсe #XX -- [ Pg.26 , Pg.338 , Pg.339 , Pg.349 ]

See also in sourсe #XX -- [ Pg.2 , Pg.120 ]




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