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Thionitrite anion

The red [SSNO] anion (37) is produced by the reaction of an ionic nitrite with elemental sulfur or a polysulfide in acetone, DMF or DMSO.115 The [SSNO] anion has a planar cis structure with a short S-S distance (1.99 A), and S-N and N-O distances of 1.67 and 1.22 A, respectively. The treatment of [SSNO]- with triphenylphosphine produces the thionitrite anion [SNO]- (38) with a bond angle of ca. 120° at nitrogen and S-N and N-O bond lengths of 1.69 and 1.21 A, respectively. [Pg.242]

See other pages where Thionitrite anion is mentioned: [Pg.165]    [Pg.323]    [Pg.165]    [Pg.323]    [Pg.164]    [Pg.242]    [Pg.4656]    [Pg.913]    [Pg.4655]    [Pg.242]    [Pg.13]   
See also in sourсe #XX -- [ Pg.242 , Pg.442 ]

See also in sourсe #XX -- [ Pg.242 , Pg.442 ]



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Thionitrites

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