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Disulfides thiolsulfinic acid ester

Disulfide monoxides Thiolsulfinic acid esters Thiosulfinyl esters 40 Thiolsulfinates 5... [Pg.550]

Tungsten trioxidefhydrogen peroxide hydrogen chloride Tliiolsulfonic and thiolsulfinic acid esters from disulfides... [Pg.55]

An irradiated soln. of di- er -butyl disulfide in methanol containing methylene blue as sensitizer treated with oxygen until uptake stops after 3.5 hrs. tert-butyl er -butanethiolsulfinate. Y 15%. F. e. s. R.W. Murray and S. L. Jindal, J. Org. Chem. 37, 3516 (1972) review of thiolsulfinic acid esters s. N. Isenberg and M. Grdinic, Intern. J. Sulfur Chem. 8, 307 (1973). [Pg.341]

Without additional reagents Disulfides and thiolsulfonic acid esters from thiolsulfinic acid esters... [Pg.192]

The 2-sulfonyloxaziridine (57) is a more selective oxidant than peracids. The reagent has been employed in the oxidation of sulfides to sulfoxides, disulfides to thiolsulfinates, selenides to selenoxides, thiols to sulfenic acids, organometallic reagents to alcohols and phenols, ketone and ester enolates to a-hydroxycarbonyl compounds (equation 31)41. The oxidation of chiral amide enolates gives optically active a-hydroxy carboxylic acids with 93-99% enantiomeric excess42. [Pg.415]

See other pages where Disulfides thiolsulfinic acid ester is mentioned: [Pg.623]    [Pg.663]    [Pg.473]    [Pg.662]    [Pg.577]    [Pg.287]    [Pg.302]   
See also in sourсe #XX -- [ Pg.31 ]

See also in sourсe #XX -- [ Pg.17 , Pg.26 , Pg.88 ]



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Disulfides acids

Disulfides esters

Thiolsulfinic acid esters

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