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Thiolactic acid, oxidation

The oxidation of thioglycolic, thiomalic, and thiolactic acids in DMSO is first-order in tetrabutylammonium-12-tungstocobaltate(III) ion. ... [Pg.223]

Oxidative Transamination. MAP and preMAP metabolites undergo transamination to o-keto acids which can then be oxidatively decarboxylated to substltuted-2-mercaptoacetlc acids and/or recLiced to substltuted-3-thiolactic acids (Equation 5]. MAP and preMAP... [Pg.306]

Another synthesis of L-3TC 228 was carried out from (2S)-3-thiolactic acid 233 in four steps."" Condensation of 233 with benzoyloxyacetaldehyde to give a separable (2 1) mixture of 234 and its C-2 diastereisomer, followed by oxidation of 234 with lead tetraacetate, yielded 235. The acetate 235 was condensed with persilylated cytosine in the presence of MesSil to obtain an a/p (1 1.3) mixture of benzoylated 3TC. [Pg.50]


See other pages where Thiolactic acid, oxidation is mentioned: [Pg.45]    [Pg.249]    [Pg.16]    [Pg.17]    [Pg.20]    [Pg.3883]    [Pg.216]    [Pg.417]    [Pg.87]    [Pg.45]    [Pg.211]    [Pg.205]    [Pg.206]    [Pg.214]    [Pg.310]    [Pg.64]    [Pg.82]    [Pg.68]   
See also in sourсe #XX -- [ Pg.99 , Pg.211 ]




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