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Thioketals Schmidt reaction

Amides lactams. Dimethyl thioketals of cyclic or acyclic ketones react with iodine azide to form an a-azido sulfide in 75-95% yield. The product rearranges to an amide or a lactam in high yield in the presence of trifluoroacctic acid. This sequence is an attractive alternative to the Beckmann rearrangement or Schmidt reaction. [Pg.211]

See other pages where Thioketals Schmidt reaction is mentioned: [Pg.821] [Pg.821]

See also in sourсe #XX -- [ Pg.6 , Pg.821 ]

See also in sourсe #XX -- [ Pg.821 ]

See also in sourсe #XX -- [ Pg.6 , Pg.821 ]

See also in sourсe #XX -- [ Pg.821 ]

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Schmidt

Schmidt reaction

Schmidt reaction reactions

Thioketal