Thioacrylamides synthesis

The dihydrothiopyran unit has been fused onto [60]fullerene through reaction with a thioacrylamide and an acyl chloride (95CC565). Cycloadditions also feature in the synthesis of... 

Among miscellaneous recent papers concerned with the reactivity of thiono- and dithio-acids and -esters [including those reporting the synthesis of 1,3-thiazine derivatives from 2-iminocyclopentanedithiocarboxylic acid, the use of chlorothionoformates for the conversion of aldoximes into nitriles, and the rapid, exothermic reaction of ethyl dithiopropionate with t-butoxy-bis(dimethylamino)methane, yielding 3-dimethylamino-2,7VA -trimethyl-thioacrylamide (181 = R = R = Me) ] is a... 

Scheme 71 The synthesis of a 2-amino-5-acylthiophenes frran 3-amino-thioacrylamides [116]...

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