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3-thio-1-alkene disulfide diaryl

Diaryl disulfides and diselenides add to alkynes to afford the (Z)-l, 2-bis(ar-ylthio)alkenes 193 and (Z)-l,2-bis(arylseleno)alkenes 194. Under CO pressure, carbonylative addition takes place to give thio esters and the selenoketones 195[I07], The selenoketones are converted into the /J-seleno-a, 3-unsaturated aldehydes 196 by Pd-catalyzed hydrogenolysis with HSnBu3[108,109],... [Pg.495]

Introduction of two different chalcogen elements to the C-C unsaturated bond is of particular interest from both synthetic and mechanistic viewpoints. Therefore, extensive studies have been carried out on the development of the (RE)2/(R E )2 binary system without using RE-E R compounds, which are difficult to prepare. (Z)-l-Seleno-2-thio-1-alkenes are produced regio- and stereoselectively when a mixture of diaryl disulfides and diaryl diselenides is subjected to a rhodium-catalyzed reaction with alkynes (Equation (68)).193... [Pg.754]


See other pages where 3-thio-1-alkene disulfide diaryl is mentioned: [Pg.2184]    [Pg.2242]    [Pg.2569]    [Pg.2569]    [Pg.2184]    [Pg.2242]    [Pg.2569]    [Pg.2569]    [Pg.1114]    [Pg.1143]    [Pg.2593]   
See also in sourсe #XX -- [ Pg.357 ]




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