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Thiazyl difluoride

The reagent NSF3 may also react via oxidative addition of an S-F bond to a metal centre to give a complex of the thiazyl difluoride anion [NSF2] , which is readily hydrolyzed to an NSO complex (Scheme 7.3). ... [Pg.134]

Thiazyl difluoride amide N-Difluoro-sulfuranyltden- ElOa, 392... [Pg.735]

A rare thiazyl difluoride complex [IrCl(F)(CO)(NSF2)(PPh3)2] 56 was prepared by the reaction of 1 and NSF3 and its X-ray crystal structure was determined. ... [Pg.274]

Urea, melamine, cyanamide, dicyandiamide, and guanidine react at elevated temperatures with sulfur tetrafluoride to give (trifluoromethyl)iminosulfur difluoride (7) in 6-25% yield.172 In the presence of sodium fluoride at 25"C, urea is converted into fluorocarbonyliminosulfur difluoride (8), but at 50°C thiazyl fluoride (9) is the main product, both formed in ca. 60% yield. At higher temperatures, carbonyl difluoride (carbonic difluoride) and sulfur hexafluoride are the sole products of the reaction of urea with sulfur tetrafluoride.173... [Pg.375]

Primary amines react with sulfur tetrafluoride to form an N=S bond. Ammonia reacts with sulfur tetrafluoride at ambient temperature in a flow system to form an unstable gas, thiazyl fluoride (N =SF. 20 Vo).193 194 The reaction with melhylamine conducted at low temperatures affords methyliminosulfur difluoride (1) with excess methylaminc, bis(melhylimino)sulfur is formed as the main product.195,196... [Pg.385]

NFS, Thiazyl fluoride, 24 16 NF2HS, Imidosulfurous difluoride mercury complex, 24 14 NFsOPSiCsHis, Phosphinimidic acid, P,P-dimethyl-iV-(trimethylsilyl)-2,2,2-trifluoroethyI ester, 25 71 NF3OSC, Imidosulfurous difluoride, (fluo-rocarbonyl)-, 24 10 NF3S, Thiazyl trifluoride, 24 12 NFjH, Ammonium, tetrafluoro-, (hydrogen difluoride), 24 43... [Pg.271]

SF3N, Thiazyl trifluoride, 24 12 SF3NOC, Imidosulfurous difluoride, (fluoro-carbonyl)-, 24 10... [Pg.294]

Thiazyl Trifluoride, NSF3, and Haloiminosulfur Difluorides, XNSF2 (X=F, Cl)... [Pg.238]

See other pages where Thiazyl difluoride is mentioned: [Pg.238]    [Pg.64]    [Pg.4654]    [Pg.421]    [Pg.4653]    [Pg.238]    [Pg.238]    [Pg.64]    [Pg.4654]    [Pg.421]    [Pg.4653]    [Pg.238]    [Pg.143]    [Pg.238]    [Pg.260]    [Pg.10]    [Pg.12]    [Pg.18]   
See also in sourсe #XX -- [ Pg.420 ]



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Thiazyl

Thiazyl Trifluoride, NSF3, and Haloiminosulfur Difluorides, XNSF2 (X F, Cl)

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