Thiazolyl disulfide

Thiazolyl sulfamic acids, rearrangement of sulfonic acid, 70 rearrangement to sulfonic acid, 75 by sulfonation, 75 2-Thiazolyl sulfenyl chloride, transformation to, thiazolyl disulfides. 412 2-Thiazolyl sulfide, in hydrocarbon synthesis, 406 oxidation of, with m-chloroperbenzoic acid, 415 with CrOj, 415 with Hj02,405,415 with KMn04,415 physical properties, infrared, 405 NMR, 404 pKa, 404 ultraviolet, 404 preparation of, from 2-halothiazoles and 5-Thiazolyl sulfides, bis-5-thiazolyl sulfide, oxidation of, 415 general, 418 5-(2-hydroxythiazolyl)phenyl sulfide case, 418 physical properties, 418 preparation of, 417-418 table of compounds, 493-496 uses of. 442 2-Thiazolyl sulfinic acid, decomposition of, 413 preparation of, from 2-acetamidothiazole sulfonyl chloride, 413 from A-4-thiazoline-2-thione and H, 0, 393,413 table of compounds, 472-473 5-Thiazolyl sulfinic add, preparation of,... 

Virus inhibitor, 140. See also Antiviral agent Vulcanization accelerators, 438,440,441 2-thiazolyl disulfides, relation with mass spectral fragmentation, 412... 

N-(2-thiazolyl)dithiocarbamates are prepared by the action of carbon disulfide on 2-aminothiazoles (see Section III.3.C and Ref. 505). When refluxed with secondary amines these heterocyclic dithiocarbamates yield l,T-dialkyl-3-(2-thiazoIyI)thioureas (261) (491). 

A-4-thiazoline-2-one, 402 thiazolyl-2-disulfides, 412 thiazolyl-2-thioethers, 405 Zirconium complexes, 156-161... 

Bis-[2-2-thiazolyl-phenyl]disulfide, (I), derivatives were also prepared by the author [2] in a subsequent investigation and were effective in reducing tire hysteresis. 

Treatment of the azirine reverse C-nucleoside 25 or its A -benzoyl derivative with carbon disulfide gave the 4-thiazolyl reverse C-nucleoside 611 (74CL519 75BCJ610) (Scheme 159). 

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