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Thianthrene 5-oxide, structure

Peroxide complexes of molybdenum(VI) are intermediates in industrially important epoxidation reactions. The so-called Mimoun-type complexes [Mo 0(02)2LaxLeq]° " (12) generally exhibit pentagonal-bipyramidal structures, with an axial 0x0 group trans to Lax and Leq, and two peroxo groups in the equatorial plane. These complexes are effective reagents for the selective oxidation of alcohols to aldehydes, amines to nitroso compounds, sulfldes to sulfoxides and then to sulfones, phenols to o-quinones, and in the sulfoxidation of thianthrene-5-oxide. [Pg.2754]

See other pages where Thianthrene 5-oxide, structure is mentioned: [Pg.316]    [Pg.34]    [Pg.948]    [Pg.969]    [Pg.975]    [Pg.893]    [Pg.948]    [Pg.969]    [Pg.975]    [Pg.644]    [Pg.1016]    [Pg.106]    [Pg.449]    [Pg.220]    [Pg.106]    [Pg.136]    [Pg.5766]   
See also in sourсe #XX -- [ Pg.129 ]



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