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Thermolysis, of perfluoroalkyl iodides

Perfluoroalkylation of substituted benzenes and heterocyclic substrates has been accomplished through thermolysis of perfluoroalkyl iodides in the presence of the appropriate aromatic compound Isomeric mixtures are often obtained W-Methylpyrrole [143] and furan [148] yield only the a-substituted products (equation 128) Imidazoles are perfluoroalkylated under LTV irradiation [149] (equation 129). 4-Perfluoroalkylimidazoles are obtained regioselectively by SET reactions of an imidazole anion with fluoroalkyl iodides or bromides under mild conditions [150] (equation 130) (for the SET mechanism, see equation 57)... [Pg.481]

See other pages where Thermolysis, of perfluoroalkyl iodides is mentioned: [Pg.81]    [Pg.81]    [Pg.269]   
See also in sourсe #XX -- [ Pg.481 , Pg.482 ]

See also in sourсe #XX -- [ Pg.481 , Pg.482 ]



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Perfluoroalkyl

Perfluoroalkyl iodides

Perfluoroalkylation

Thermolysis, of perfluoroalkyl

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