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Thermodynamic Infrastructure, States, and Fluctuations

There were three themes of the previous chapter. First was the infrastructure for describing systems via potentials, state variables, and differentials. Second was the use of empirical equations to model systems at equilibrium. Third, was that fluctuations impose a nonzero width on every state point. A point anticipated by the ideal gas, van der Waals, or other equations of state is not infinitely sharp as in analytic geometry. Rather, a system demonstrates a range of pressure, density, and other properties. The fluctuations are as integral to the thermodynamic behavior as the average values. [Pg.89]


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Infrastructure

State, thermodynamic

Thermodynamic fluctuations

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