Thermodynamic data thiazole

Thiazole, 2-methylthio-4-isopropyl-thermodynamic data, 6, 291 (79HC(34-2)1, p. 407) Thiazole, 2-methylthio-4-methyl-... 

Thiazole, 2,4,5-trimethyl-thermodynamic data, 6, 245 (66CR(C)(263)1333) Thiazole, 2,2,4-trimethyl-4,5-dihydro- H NMR, 5, 17 (64JCP613)... 

Thiazole, 2-methylthio-4-isopropyl-thermodynamic data, 6, 291 (79HC(34-2)1, p. 407) Thiazole, 2-methylthio-4-methyl-thermodynamic data, 6, 291 (79HC(34-2)1, p. 407) Thiazole, 2-nitro-PE, 6, 240 <79HC(34-1)26, p. 52)... 

The thermodynamic study of thiazole and of some of its binary mixtures with various solvents has led to the determination of important practical data, but also to the discovery of association phenomena between thiazole and some solvents and of thiazole self-association. 

K (66.46 e.u.) with the spectroscopic value calculated from experimental data (66.41 0.009 e.u.) (295, 289) indicates that the crystal is an ordered form at 0°K. Thermodynamic functions of thiazole were also determined by statistical thermodynamics from vibrational spectra (297, 298). 

In all its reactions the lone pair of thiazole is less reactive than that of pyridine. Table 1-61 shows three sets of physicochemical data that illustrate this difference. These are (1) the thermodynamic basicity, which is three orders of magnitude lower for thiazole than for pyridine (2) the enthalpy of reaction with BF3 in nitrobenzene solution, which is 10% lower for thiazole than for pyridine and (3) the specific rate of quaterni-zation by methyl iodide in acetone at 40°C, which is about 50% lower for... 

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