Thermal second-generation systems

The thermal energy generated or absorbed by an electrochemical cell is determined first by the thermodynamic parameters of the cell reaction, and second by the overvoltages and efficiencies of the electrode processes and by the internal resistance of the cell system. While the former are generally relatively simple functions of the state of charge and temperature, the latter are dependent on many variables, including the cell history. 

The first-generation OTM modules were assembled and tested. The reactor for the pilot-scale syngas plant was delivered and installed. Until 2015, the OTM-based oxy-combustion project is expected to have delivered the second generation of improved OTM modules that will be tested for their performance and hilly integrated on a development scale of a 1 megawatt thermal (MWth) oxy-combustion system (Figure 4.20) [103]. 

FIRAC is a computer code designed to estimate radioactive and chemical source-terms as.sociaied with a fire and predict fire-induced flows and thermal and material transport within facilities, especially transport through a ventilation system. It includes a fire compartment module based on the FIRIN computer code, which calculates fuel mass loss rates and energy generation rates within the fire compartment. A second fire module, FIRAC2, based on the CFAST computer code, is in the code to model fire growth and smoke transport in multicompartment stmetures. 

Hollow carbon nanotubes (CNTs) can be used to generate nearly onedimensional nanostrutures by filling the inner cavity with selected materials. Capillarity forces can be used to introduce liquids into the nanometric systems. Here, we describe experimental studies of capillarity filling in CNTs using metal salts and oxides. The filling process involves, first a CNT-opening steps by oxidation secondly the tubes are immersed into different molten substance. The capillarity-introduced materials are subsequently transformed into metals or oxides by a thermal treatment. In particular, we have observed a size dependence of capillarity forces in CNTs. The described experiments show the present capacities and potentialities of filled CNTs for fabrication of novel nanostructured materials. 

Sulphuric acid at 93% was added to p-nitrotoluene. The temperature reached 160°C due to a failure of the thermal control system. The sulphonic acid formed decomposed violently at this temperature. The post-accident investigation showed that the decomposition started between 160 and 190 C. In fourteen minutes the temperature rose to 190-224°C and in one minute and thirty seconds to 224-270°C. A large volume of gas was then released during the eruption. The phenomena caused by the decomposition of nitrated derivatives in the presence of sulphuric acid will be addressed several times. What these incidents have in common is the formation of large carbonised volumes. This phenomenon is common with sulphonic acids. The nitro group role is to destabilise intermediate compounds and final compounds and to generate... 

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