Thermal point bonding

Point bonding, 27 474, 476. See also Thermal point bonding Point-contact transistor, 9 730-731 Point of departure, 25 244 Point of incipient precipitatioi,... 

Michielsen, S., Poirrdeyhimi, B., and Desai, R, Review of Thermally Point-Bonded Nonwovens Materials, Processes, and Properties , Journal... 

The first of these points seeks to avoid initial attack by eliminating thermally labile bonds from the structure the second suggests one way of limiting the damage once a bond has been broken. 

Caleulations by the more rigorous proeedure yield, in MM3, a sum of (a) bond energies, (b) steric energy, (c) vibrational zero point and thermal energies, and (d) structural features POP and TORS. Energies (a), (b), and (d) are calculated as before. Bond energy parameters appear to be quite different from those of the default MM3 calculations canied out so far because zero point and thermal energies are not included in the parameters but are added later. 

The high degree of crystallization and the thermal stability of the bond between the benzene ring and sulfur are the two properties responsible for the polymer s high melting point, thermal stability, inherent flame retardance, and good chemical resistance. There are no known solvents of poIy(phenyIene sulfide) that can function below 205°C. 

Isomerization. Maleic acid is isomerized to fumaric acid by thermal treatment and a variety of catalytic species. Isomerization occurs above the 130 to 140°C melting point range for maleic acid but below 230°C, at which point fumaric acid is dehydrated to maleic anhydride. Derivatives of maleic acid can also be isomerized. Kinetic data are available for both the uncatalyzed (73) and thiourea catalyzed (74) isomerizations of the cis to trans diacids. These data suggest that neither carbonium ion nor succinate intermediates are involved in the isomerization. Rather, conjugate addition imparts sufficient single bond character to afford rotation about the central C—C bond of the diacid (75). 

Smooth surfaces are normally estabflshed by calendering, a process which subjects the fabric at the nip point(s) of two or more roUs to the influence of controlled time, temperature, and pressure. When calendering is used as a thermal-bonding process, the roUs are of the same dimension and composition and are independently driven. However, when calendering is used as a fabric finishing operation, the roUs are frequently of different dimensions and composition and are not always independently driven. 

Vitreous sihca has many exceptional properties. Most are the expected result of vitreous sihca being an extremely pure and strongly bonded glass. Inert to most common chemical agents, it has a high softening point, low thermal expansion, exceUent thermal shock resistance, and an exceUent optical transmission over a wide spectmm. Compared to other technical glasses, vitreous sihca is one of the best thermal and electrical insulators and has one of the lowest indexes of refraction. 

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