Theoretical analysis CIDNP

Theoretical Analysis of MFEs, CIDNP, and CIDEP with the Density Matrix Method... 

The theoretical analysis of MEFs and CIDNP due to the S-Tq mixing can be carried out with Eqs. (11-57). With these equations, the theoretical calculation of MEFs and CIDNP due to the S-Tq mixing is possible. In Chapter 12, typical results of such an analysis of MFEs will be shown. The theoretical analysis of CIDEP due to the S-To mixing can also be carried out with the density matrix method as shown in the following part of this section [5]. The electron spin polarization (P ) of radical A in a nuclear state (a) can be written as... 

For example, the above-mentioned qualitative rules are applicable for the analysis of CIDNP effects for all nuclei from Table 1, except for ii Sn, which has a number of peculiarities stipulated by its anomalous magnetic resonance parameters (hyperfine constant more than 0.16 T, g-factor 2.0160). To analyse CIDNP effects of this nucleus one has to employ a special theoretical approach. 

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