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The Peterson and Related Reactions

Peterson reactions offer interesting and unique profiles, such as high stereoselectivity and sufficiently high reactivity to allow reactions with either ketones, aldehydes, or other carbonyl compounds bearing various functional groups. The [Pg.18]

Stereochemistry and the Reaction Mechanism of the Peterson Reaction of /f-Hydroxyallcylsilanes [Pg.19]

Kano, N. Kawashima, T. The Peterson and Related Reactions in Modem Carbonyl Olefination Takeda, T. (ed.), Wiley-VCH Weinheim, Germany, 2004, 18—103. (Review). [Pg.459]

The Peterson olefination is a two-step process for the formation of alkenes from an a-silylcarbanion and an aldehyde or ketone. The first step is an addition reaction that affords both syn and anti p-hydroxysilanes. The stereochemistry is then controlled during the elimination step by using either an acid or a base. Reviews Kano, N. Kawashima, T. In Modem Carbonyl Olefination-Methods and Applications Takeda, T. Ed. Wiley-VCH Weinheim, 2004 Chapter 2 The Peterson and Related Reactions, pp. 18-103. (b) Kelly, S. E. In Comprehensive Organic Synthesis Trost, B. M. Fleming, 1., Eds. Pergamon Oxford, 1991 Vol. 1, Chapter 3.1 Alkene Synthesis, pp. 731-737. (c) Ager, D. J. Org. React. 1990, 38, 1-223. (d) Ager, D. J. Synthesis 1984, 384-398. [Pg.184]

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Peterson

Peterson reaction

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