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The One-Carbon Atom Ring Insertion

1) For a review on one carbon ring expansions of bridged bicyclic ketones, see ref. [2]. [Pg.5]


Hydroxylation is the attachment of -OH groups to hydrocarbon chains or rings. Aliphatic hydroxylation of alkane chains can occur on the terminal carbon atom (-CH3 group or co-carbon) or on the C atom next to the last one (co-1 -carbon) by the insertion of an O atom between C and H, as shown below for the hydroxylation of the side chain on a substituted aromatic compound ... [Pg.163]

In 1968, an excellent review on Carbocyclic Ring Expansion Reactions was published [1], Most of the reaction discussed there are one carbon atom insertions. Our review will be limited to discussions of newer methods. Well known reactions are summarized only by giving the principal reaction and leading additional references. The principal reactions for one carbon insertion are summarized in Scheme II/l. [Pg.5]


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Atom Insertion

Carbon insertion

Ring Carbon

Ring one carbon

THE CARBON ATOM

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