The Mobility of Ions in Solution

The conductivity of aqueous ions and their self-diffusion are dealt with in Sections 

1 and 2.3.2.2. Here snch information concerning ions in nonaqueous solvents is briefly presented. 

Einstein [93] derived from the Navier-Stokes differential equations for a sphere moving in a viscons medinm an expression for the diffusion coefficient D for such spheres that may be rewritten as  

Ion MeOH EtOH PrOH EG PC NH3 FA DMF MeCN HMPT DMSO TMS 1,2DC  

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The mobility of ions in solution varies with the solution temperature. Ionic solutions will increase conductivity about 2 % for every degree increase in temperature. Conductivity detectors usually compensate automatically for temperature change by... 

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