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The General Expression for a Binary System

Wohl (1946) expressed the molar excess Gibbs free energy in a binary solution in terms of a power series of the effective volume fractions of the two components, Zj and Zi (Prausnitz)  [Pg.465]

The following two expressions, that of van Laar and that of Margules, can be obtained as special cases of Eq. 13.11.1, even though they were developed earlier. [Pg.465]


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