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The dynamic response of polymer electrolytes

A method of characterising transport mechanisms in solid ionic conductors has been proposed which involves a comparison of a structural relaxation time, t, and a conductivity relaxation time, t . This differentiates between the amorphous glass electrolyte and the amorphous polymer electrolyte, the latter being a very poor conductor below the 7. A decoupling index has been defined where [Pg.139]

The simplest model involves ion hopping between sites on a lattice (not fixed as in a solid electrolyte such as Agl) with the ions obeying a hopping type equation [Pg.140]

Pj is the probability of finding a mobile ion at site i, Wij is the probability per unit time that an ion will hop from site j to site i and is equal to zero [Pg.140]

In addition to specific applications, the dynamic bond percolation model has been extended to focus on the importance of lattice considerations. The role of correlations among different renewal processes and the [Pg.142]


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