The BrO CIO Reaction Free-radical Channels

The BrO + CIO Reaction Free-radical Channels.—The BrO - - QO reaction proceeds at 298 K via two channels (SOa) and (SOb), both having rate constants equal to 6.7 x 10-. An analysis of reaction (SOa) similar to that already carried 

A direct study at 298 K of reaction (53) using mass spectrometry has been carried out. BrO radicals were xroduced by the reaction of O / atoms with excess Bt2, viz. O + ftri - BrO + Br. The rate constant for NO BrO, 5 = (2.2 0.4) x 10 , is close to that for the NO -I- CK) reat on. No temperature co hacat for NO -I- BrO has been reported yet. The existing data for the rate constant for the reaction of O with BrO ate dmved from kinetic 

---