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Thallium trinitrate ketones

Thallium trinitrate, TI(N03)3 3H20 (mp 102-105 C), oxidizes phenols and dihydroxy aromatic compounds to quinones [409, acetylenes to a-hydroxy ketones, a-diketones, or carboxylic acids 413] and methyl ketones to a-keto acids [414],... [Pg.17]

Another way of oxidizing aryl methyl ketones without degradation is by their reaction with thallium trinitrate in methanolic solution and in the... [Pg.205]

Ferraz HMC, Silva LF Jr. Thallium trinitrate mediated ring contraction of monocychc ketones stereochemical aspects. Tetrahedron Lett. 1997 38 1899-1902. [Pg.518]

E. C. Taylor, A. McKillop, and coworkers. Thallium in organic synthesis 49. Oxidative rearrangement of chalcone dimethylketals to methyl-2,3-diaryl-3-methoxypropanoates with thallium(m) trinitrate in trimethylorthoformate. J. Org. Chem., 1977, 42, 4167 50. A convenient synthesis of thallium(i) cyanide, a useful reagent in organic synthesis (for conversion of aroyl chlorides to aromatic a-ketonitriles). J. Org. Chem., 1978, 43, 2280 51. Oxidation of enolizable ketones to a-nitratoketones by thallium(in) nitrate in acetonitrile. [Pg.109]

See other pages where Thallium trinitrate ketones is mentioned: [Pg.154]    [Pg.827]    [Pg.833]    [Pg.154]    [Pg.827]    [Pg.833]    [Pg.210]    [Pg.210]    [Pg.378]    [Pg.509]    [Pg.521]    [Pg.913]    [Pg.1069]    [Pg.154]    [Pg.827]    [Pg.833]    [Pg.845]    [Pg.845]    [Pg.845]   
See also in sourсe #XX -- [ Pg.154 ]

See also in sourсe #XX -- [ Pg.154 ]

See also in sourсe #XX -- [ Pg.7 , Pg.154 ]

See also in sourсe #XX -- [ Pg.7 , Pg.154 ]

See also in sourсe #XX -- [ Pg.154 ]



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