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Thallium triacetate allylic oxidation

Oxidation of olefins. Kabbe explored briefly the oxidation of cyclohexene, styrene, and o-allylphenol and expressed the view that thallium triacetate is intermediate between lead tetraacetate and mercuric acetate. Anderson and Winstein followed the oxidation of cyclohexene in acetic acid at room temperature (several days) by vapor-phase chromatography and accounted quantitatively for all the five products formed the cij-and rrans-diacetates (1 and 2), the ring-contracted diacetate (3) and aldehyde (4), and the product of allylic oxidation (5). In dry solvent the transdiacetate (2) predominated, and in moist solvent the cis-diacetate (I) predominated. [Pg.578]

See other pages where Thallium triacetate allylic oxidation is mentioned: [Pg.92]    [Pg.92]    [Pg.92]   
See also in sourсe #XX -- [ Pg.92 ]

See also in sourсe #XX -- [ Pg.92 ]

See also in sourсe #XX -- [ Pg.7 , Pg.92 ]

See also in sourсe #XX -- [ Pg.7 , Pg.92 ]

See also in sourсe #XX -- [ Pg.92 ]



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Allyl oxide

Allylic oxidation

Oxidation thallium

Thallium oxides

Thallium triacetate

Triacet

Triacetate

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