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Thallium hydrotris

Chemistry, syntheses, and applications of thallium(I) hydrotris(pyrazolyl)borate [TpTl(I)] 98MI44. [Pg.252]

A tris(imidazolyl)borate (138) complex of thallium(I) has been synthesized.The solid-state structure of hydrotris(imidazolyl)boratothallium(I) consists of one-dimensional, twisted, ladderlike strands, and three-coordinate thallium centers. Due to the position of the nitrogen donors, the tris(imidazolyl)borate ligand is not capable of forming metal chelates as are observed in tris(pyrazolyl)borates. Poly(benzotriazolyl)borate ligands have some features of both tris(pyrazo-lyl)borate and tris(imidazolyl)borate systems. Thallium(I) complexes of bis-, tris-, and tetrakis (benzotriazolyl)borates are reported. These adducts have been synthesized by treating the corresponding potassium derivative with an equimolar quantity of thallium(I) formate. ... [Pg.444]

See other pages where Thallium hydrotris is mentioned: [Pg.189]    [Pg.218]    [Pg.189]    [Pg.218]    [Pg.170]    [Pg.181]    [Pg.218]    [Pg.223]    [Pg.225]    [Pg.124]    [Pg.188]    [Pg.171]    [Pg.206]    [Pg.219]    [Pg.224]    [Pg.226]    [Pg.70]   


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