Thallium, dithiocarbamate complexes

The (IsQ-coordinated species [Mo(CO)3(py)3] prepared from [Mo(CO)6] and pyridine is useful for the synthesis of various jr-allyl molybdenum compounds (68JOM(13)Pl, 970M5365). The 3-allyl complexes [( 3-allyl)Mo(CO)2Br(py)2] form [( 3-allyl)Mo(CO)2(S,S)(py)] with the anionic S,S-donors, dithiocarbamates and xanthates of sodium and potassium, M (S,S) (81JOM(218)185). [( 3-C3H5)Mo(CO)2(py)2Br] (68JO M(14)375) with thallium hexafluorophosphate in acetonitrile gives... 

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