Thallium -chloride. tetrahydrate

Thallium(lll) chloride tetrahydrate TICI3-4H30 13463-32-2 382.804 orth cry 3.00 sH,0... [Pg.744]

The synthesis of a-aminonitriles from aldehydes, amines and trimethylsilyl cyanide can be catalysed by thallium(m) chloride. Thus, reaction of several aromatic and aliphatic aldehydes with aniline or benzylamine in the presence of 1 mol% of thallium(iii) chloride tetrahydrate in solvent-free conditions smoothly led to several a-aminonitriles in good to excellent yields (Scheme 20.1). [Pg.213]

C5H18CaCl209, a-L-Arabinose calcium chloride tetrahydrate, 44B, 389 CsHi9BaOi3P, Barium ribose-5-phosphate pentahydrate, 27, 792 CsHyNaOs, Sodium ascorbate, 34B, 247 CgHyOgTl, Thallium(I) L-ascorbate, 39B, 298... [Pg.215]

Thallium (ITT) fluoride has been prepared by the action of fluorine or bromine trifluoride on thaUium(III) oxide at 300°C. It is stable to ca 500°C but is extremely sensitive to moisture. Thallium (ITT) chloride can be obtained readily as the tetrahydrate [13453-33-3] by passing chlorine through a boiling suspension of HCl in water. It can be dehydrated with thionyl chloride. Thallium (ITT) bromide tetrahydrate [13453-29-7] is prepared similarly, whereas the iodide prepared in this manner is thaUium(I) triiodide [13453-37-7] H" F2-... [Pg.468]

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