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Thallium-catalyzed epoxidation

Thallium-Catalyzed Epoxidation Process. The use of Tl(III) for olefin oxidation to yield glycols, carbonyls, or epoxides is weU known... [Pg.461]

The in situ catalysts formed from diethyl tartarate (DET) and titanium(IV) isopropoxide catalyze the asymmetric epoxidation reactions (72). The seminal work of Sharpless has been applied for a great variety of synthetic reactions. (The replacement of titanium with zirconium, hafnium, or thallium does not improve the chiral efficiency)... [Pg.687]

See other pages where Thallium-catalyzed epoxidation is mentioned: [Pg.104]    [Pg.184]    [Pg.36]    [Pg.313]   


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Epoxides catalyzed

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