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Tetranuclear thiocyanates

The dinuclear complex [(H3N)5Ru(/i-N2)Ru(NH3)5] has an aquation rate constant >10 s at room temperature, much faster than that for [Ru(NH3)5(N2)]. The tetranuclear cation [Ru4(OH)4] undergoes depolymerization, presumably giving initially [Ru2(OH)2], much more slowly. At 298 K the depolymerization rate constant is 2.5xl0 s = 63kJmorO. Linkage isomerization of complexes [Ru(NCS) -(SCN)6 ] n = 1-4), produced by reacting ruthenium trichloride with potassium thiocyanate in aqueous solution, under various conditions has been discussed in qualitative terms. ... [Pg.237]

See other pages where Tetranuclear thiocyanates is mentioned: [Pg.115]    [Pg.217]    [Pg.217]    [Pg.453]    [Pg.479]    [Pg.565]    [Pg.584]    [Pg.539]    [Pg.538]    [Pg.3292]    [Pg.5438]    [Pg.256]    [Pg.258]    [Pg.151]   
See also in sourсe #XX -- [ Pg.5 , Pg.733 ]



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Tetranuclear

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