Tetranitromethylaniline

Amino-1,2,4-triazole is a useful starting material for the synthesis of many 1,2,4-triazole-based explosives. Jackson and Coburn synthesized a number of picryl- and picrylamino-substituted 1,2,4-triazoles. PATO (99) is synthesized from the reaction of 3-amino-1,2,4-triazole (98) with picryl chloride (67). ° PATO has also been synthesized from the reaction of 3-amino-l,2,4-triazole with A,2,4,6-tetranitromethylaniline (tetryl). PATO has a low sensitivity to impact and is thermally stable up to 310 °C. PATO (VOD 7469 m/s) exhibits lower performance to TATB (VOD 8000 m/s) which is the common benchmark standard for thermal stability and insensitivity in explosives. 

Tetryl is a widely-used explosive. It is also known under the names of Pyronite, Tetrylit, Tetralite, Tetralita. In England it has been known for some time as Composition Exploding—CE. The incorrect name—tetranitromethylaniline—may sometimes be encountered in the literature. 

N.N -D imethyl-2,4,6-trinitro-m-pbenylene-diamine, (02N)3C6H(NH.CH3)2 yel crysts, mp 235—40° (dec), bp — explodes on heating to high temp was prepd by treating 2,3,4 6 tetranitromethylaniline with an aq soln of methylamine (Refs 2,4, 5 6)... 

TeNMA. Tetranitromethylaniline (USA) see in this Vol under Tetryl and in Vol 8, M101-R... 

TAX symbol for 1-acetylhexahydro -3,5-dinitro-s-triazine TeNMA or 1 TeNMeA / tetranitromethylaniline... 

Wells HG, Lewis JH, Sansum WD, et al. 1920. Observations of the toxicity of tetranitromethylaniline (tetryl), tetranitroxylene (T.N.X), tetranitraniline (T.N.A), dinitrodichlorobenzene (parazol), and metanitraniline. Journal of Industrial Hygiene 2 247-252. 

Tar in Explosives, 105 Tartrates, 109 Teasing machine, 93 Tetranitroaniline, 102 Tetranitrodiglycerine. 91 Tetranitroethylaniline, 106 Tetranitromethane, 105 Tetranitromethylaniline, 106 Tetranitronaphthalene, 102 I etranyl, 102 Tetryl, 106... 

Tetryl, also called tetranitromethylaniline, has a melting point of about 130°C with some decomposition. It is nonhygroscopic and practically insoluble in water but highly soluble in acetone and benzene. It can be stored for over 20 years at ambient temperatures with no noticeable change in properties. 

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