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Tertiary amines conformational analysis

C—N bond lengths in tertiary amines. Experimental and ab initio calculations have demonstrated the gradual decrease in C—N bond lengths when going from primary (CH3NH2) to secondary ((CH3)2NH) to tertiary ((CHsjsN) amines. However, when a tertiary amine is incorporated in an anomeric unit, the cumulative effect of anomeric interactions, steric interactions and conformationally independent C—X bond shortening add up to level off this trend. Moreover, a statistical analysis of C—N bond lengths in... [Pg.16]

See other pages where Tertiary amines conformational analysis is mentioned: [Pg.16]    [Pg.43]    [Pg.50]    [Pg.54]    [Pg.315]    [Pg.298]    [Pg.350]    [Pg.358]    [Pg.751]    [Pg.43]    [Pg.53]    [Pg.54]    [Pg.3305]    [Pg.2073]    [Pg.53]    [Pg.152]    [Pg.215]    [Pg.70]    [Pg.124]    [Pg.111]   
See also in sourсe #XX -- [ Pg.43 , Pg.44 , Pg.45 , Pg.46 , Pg.47 , Pg.48 , Pg.49 , Pg.50 , Pg.51 , Pg.52 , Pg.53 , Pg.54 ]

See also in sourсe #XX -- [ Pg.43 , Pg.44 , Pg.45 , Pg.46 , Pg.47 , Pg.48 , Pg.49 , Pg.50 , Pg.51 , Pg.52 , Pg.53 , Pg.54 ]



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