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Terpyridyl redox properties

Optical measurements have been reported for [Ru(bipy)3], [Ru(bipy)2(biq)f, and [Ru(biq)3] (biq = 2,2 -biquinolyl) together with the temperature dependence (84—330 K) of the luminescence emission. The behaviour of the three complexes is rationalized in terms of states derived from a simple orbital model. A description of the photophysical and redox properties of the luminescent complexes [RuLL L ] (where L = 2,2 -bipyridyl, L = 2,2, 2"-terpyridyl, and L" = phenothiazine, N-methylphenothiazine, thian-threne, or H2O) has appeared, and this suggests that states other than the luminescent state are populated. Coupling between dissimilar ligands in the excited states of [Ru(bipy) (phen)3 f, [Ru(bipy) L3 and... [Pg.174]

See other pages where Terpyridyl redox properties is mentioned: [Pg.115]    [Pg.184]    [Pg.185]    [Pg.1299]    [Pg.1299]    [Pg.4753]    [Pg.4753]    [Pg.311]    [Pg.15]    [Pg.107]    [Pg.367]   
See also in sourсe #XX -- [ Pg.4 , Pg.543 ]



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Redox properties

Terpyridyls

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