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Termination due to improper addition of monomers

When the monomer is attached to the active centre in a manner leading to the formation of a weakly reactive ion, growth is terminated. A typical example of this kind of termination is the formation of an unreactive ion during cationic polymerization of vinyl carbazole. Instead of propagation [Pg.426]

The generated ion does not react with monomer. It easily combines with the counter-ion. [Pg.426]


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Additives monomers

Improper

Monomers termination

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