Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Terminal nitrido complexes

OsmiumfVI).—The preparation and properties of the new terminal nitrido-complexes R[Os(N)X4] (X = Cl or Br R = Ph4As or Bu N) have been described. A preliminary investigation of the slow hydrolysis of [OsP ] has been carried out, from which the initial product appears to be [OsOp4]. ... [Pg.361]

Schoffel J, Susnjar N, Niickel S, Sieh D, Burger P. 4d vs. 5d—reactivity and fate of terminal nitrido complexes of rhodium and iridium. Eur J Inorg Chem. 2010 4911-4915. [Pg.374]

The binuclear complex [Mo2Cl2N2o] features a terminal nitrido ligand, N=, as well as terminal and bridging azido ligands, i.e. [ (MoCl(N)(t, -N,)2(/t,t -Nt)l2] Concatenations larger than N3 are rare. The planar bridging N4... [Pg.419]

The reactivity of terminal nitrido ligands towards acidic fragments has been used for the synthesis of imido derivatives starting from the neutral rhenium(V) complex... [Pg.330]

A related process has been reported for the synthesis of osmium nitrido complexes with 1,2-benzenedithiolate ligands. Thus, the synthesis of 173 was effected by treatment of (Bu4N)[OsNC14] with deprotonated 1,2-benzenedithiol (Eq. (70)). Interestingly, when 173 is treated with Me3OBF4 alkylation is observed to occur on the sulfur this contrasts the reaction of 173 with Ph3CPF6, for which reaction at the terminal nitride is observed [93]. [Pg.163]

The complex OsjN Hj, , made from 0s04 and ammonia,344 is possibly OsjN3(OH)5(NH3)4, with a structure related to that of Figure 21 but having an extra terminal nitrido ligand at the central atom (Y site).344... [Pg.564]

See other pages where Terminal nitrido complexes is mentioned: [Pg.3]    [Pg.8]    [Pg.559]    [Pg.4990]    [Pg.4989]    [Pg.559]    [Pg.4013]    [Pg.361]    [Pg.283]    [Pg.302]    [Pg.373]    [Pg.56]    [Pg.3]    [Pg.8]    [Pg.559]    [Pg.4990]    [Pg.4989]    [Pg.559]    [Pg.4013]    [Pg.361]    [Pg.283]    [Pg.302]    [Pg.373]    [Pg.56]    [Pg.435]    [Pg.198]    [Pg.318]    [Pg.319]    [Pg.325]    [Pg.327]    [Pg.1250]    [Pg.1341]    [Pg.43]    [Pg.129]    [Pg.161]    [Pg.54]    [Pg.55]    [Pg.55]    [Pg.111]    [Pg.189]    [Pg.194]    [Pg.560]    [Pg.2517]    [Pg.4965]    [Pg.629]    [Pg.629]    [Pg.423]    [Pg.167]    [Pg.419]    [Pg.358]    [Pg.358]    [Pg.159]    [Pg.2516]    [Pg.4964]    [Pg.189]    [Pg.194]   
See also in sourсe #XX -- [ Pg.55 ]



SEARCH



Nitrido

Nitrido complexe

Nitrido complexes

Terminal complex

Terminator complexes

© 2024 chempedia.info