Temperature coefficient of activation

Measurements of the temperature coefficient of activation/ the volume of activation/ and the entropy of activation have also been reported for the cyclization of 4-chloro-l-butanol. While there are some differences of opinion as to the interpretation of these values/ support of the kinetic evidence of a weakly anchimerically assisted process is indicated. 

In this equation for the temperature coefficient of activity, H i and H are the partial heat contents of the component in a given solution and in the standard state to which F refers and Lj = H] — Hj is the heat content relative to the standard state. 

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