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Tantalum, organometallic chemistry

Monomeric, paramagnetic chlorohydrides snch as MH2CI2 (PR3)4 derive from facile oxidative addition of H2 to MCl2(PR3)4 complexes. Of these 17e dodecahedral complexes, (32) is the most interesting (eqnation 17). Its thermolysis in solution offers a qnadruply bridged hydride (33) and it can also be rednced to a monomeric Ta 16e species (34). Ta hydrides display a hydridic character (see Hydride Complexes of the Transition Metals), as shown by the reduction of CO by cyclopentadienyl derivatives. (see Niobium Tantalum Organometallic Chemistry)... [Pg.2943]

Metal-mediated Protein Modification Niobium Tantalum Organometallic Chemistry Polynuclear OrganometaUic Cluster Complexes. [Pg.2952]

Based in part on the article Niobiiun Tantalum Organometallic Chemistry by David E. Wigley which appeared in the Encyclopedia of Inorganic Chemistry, First Edition. [Pg.2955]

Carbonyl Complexes of the Transition Metals Mechanisms of Reaction of Organometallic Complexes Niobium Tantalum Organometallic Chemistry. [Pg.5056]

See other pages where Tantalum, organometallic chemistry is mentioned: [Pg.480]    [Pg.1572]    [Pg.2930]    [Pg.2947]    [Pg.2951]    [Pg.2955]    [Pg.2955]    [Pg.2956]    [Pg.2957]    [Pg.2958]    [Pg.2959]    [Pg.2960]    [Pg.2961]    [Pg.2962]    [Pg.2963]    [Pg.2964]    [Pg.2965]    [Pg.2966]    [Pg.2967]    [Pg.2968]    [Pg.2969]    [Pg.2970]    [Pg.2971]    [Pg.2972]    [Pg.2973]    [Pg.2974]    [Pg.2975]    [Pg.2976]    [Pg.2977]    [Pg.2978]    [Pg.2979]    [Pg.2980]    [Pg.2981]    [Pg.2982]    [Pg.2983]    [Pg.3214]    [Pg.5321]    [Pg.2934]    [Pg.2946]    [Pg.2950]    [Pg.2954]    [Pg.2954]    [Pg.2955]   
See also in sourсe #XX -- [ Pg.480 ]



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