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Tantalium complexes

Likewise, imido tantalium complexes 176 undergo exchange reactions with N-t-butyl-N -... [Pg.35]

Carbodiimides also insert into Ta—N bonds in a mixed tantalium amido/imido complex. Pentacoordinated phosphoranes, such as 413, react with DCC or diisopropylcarbodi-imide to give hexacoordinate phosphorus amidinates 414 ... [Pg.81]

The reaction of bis(trimethylsilyl)carbodiimide with Li(2,4,6-tri-i-PrPh) affords a ben-zamidinato anion which on reaction with MeCb (Me = Nb, Ta) affords the niobium and tantalium benzamidinato complexes... [Pg.191]

The insertion products of diphenylcarbodiimide into Ti(0-i-Pr)4 carry out metathesis reactions at elevated temperatures by insertion of an equivalent of carbodiimide in a head to head fashion followed by an extrusion reaction Also, insertion into a Ti-C bond is observed in the reaction of CpTiMcs with carbodiimides to form CpTiMe2[NRC(Me)NR] Insertion into Ti-C bonds is also observed in the reaction of diisopropylcarbodiimide with imido titanium cations Carbodiimides also insert into Ta-N bonds in a mixed tantalium amido/imido complex... [Pg.217]

See other pages where Tantalium complexes is mentioned: [Pg.35]    [Pg.35]   
See also in sourсe #XX -- [ Pg.79 , Pg.170 ]

See also in sourсe #XX -- [ Pg.79 , Pg.170 ]



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