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Tangency, phase-space transition states

The first method comes from the idea that the connections among normally hyperbolic invariant manifolds would form a network, which means that one manifold would be connected with multiple manifolds through homoclinic or heteroclinic intersections. Then, a tangency would signify a location in the phase space where their connections change. This idea offers a clue to understand, based on dynamics, those reactions where one transition state is connected with multiple transition states. In these reaction processes, the branching points of the reaction paths and the reaction rates to each of them are important We expect that analysis of the network is the first step toward this direction. [Pg.176]


See other pages where Tangency, phase-space transition states is mentioned: [Pg.563]    [Pg.145]    [Pg.156]   


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