System Peaks with the Equilibrium-Dispersive Model

System Peaks with the Equilibrium-Dispersive Model 

4 Application of System Peaks to Analyte Peak Compression. 622 

1 High-Concentration System Peaks for a Single-Component Sample. 627 

When some of the components of the mobile phase are adsorbed by the stationary phase, the chromatograms of even small samples are not predicted correctly by linear chromatography. Then the sample injection causes a perturbation of their equilibrium, which is not properly described by linear chromatography im-less the equilibrium isotherms of these adsorbed components of the mobile phase are linear. There are basically two types of situations that may arise. They are typically exemplified by normal and reversed phase chromatography. In the for- 

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