Synthesis, Structures and Protolyses of Metal III Amides

Tris(pyrrolido)arsenic, unlike the isoleptic robust P analogue, decomposed at ambient temperamre, while the Sb and Bi compounds proved to be inaccessible from the MCl3/3Li-(NC4H4) system. Whereas MCl3/3Li[N(H)C6H2Bu 3-2,4,6] furnished the thermally 

3 Synthesis, Structures and Reactions of Heteroleptic Mononuclear Bis(aniido)- 

The following mononuclear bis(amido)metal(III) compounds were reported in the post- 

Sb(NEt2)3 HN(C6p5)(C5H4N-2) [SbE(NEt2) N(C6E4NEt2-2)(C5H4N-2))] 30b 

Bi(NMe2)3 HN(C6P5)(C5H4N-2) BiE2[N C6E3(NMe2)2-2,6)(C5H4N-2)] 16c 

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