Synthesis of naturally occurring phenylpropenoid 3-D-glucopyranoside

Reaction of ally I tetraacetyl P-D-glucopyranoside and phenyl boronic [Pg.282]

The MH-type reaction of phenylboronic acids and conjugated olefins, such as butyl acrylate, acrylnitrile, and methyl vinyl ketone under Pd(0)-catalyzed [Pg.283]

Synthesis of phenylpropenoid fi-D-glucopyranoside using MH-type reaction [Pg.284]

The MH-type reaction of silanols and organotin compounds with olefins via a Pd(II)-mediated pathway has been reported by Hiyama and co-workers. Based on this pathway, a plausible MH-type reaction mechanism with arylboronic acids was presented in Fig. 26. According to this mechanism, the aryl unit migrated to [Pg.284]

Reaction of arylboronic acid with allyl-2,3,4,6-tetra-0-acetyl-P-D-glucopyranoside [Pg.285]

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