Synthesis of Bacterial Cell Envelope Components

Synthetic Cellular Chemistry Laboratory, RIKEN, Saitama, Japan 

Glycochemical Synthesis Strategies and Applications, First Edition. 

Edited by Shang-Cheng Hung and Medel Manuel L. Zulueta. 

FIGURE 14.1 Cell envelope structures of (a) Gram-negative bacteria, (b) Gram-positive 

SCHEME 14.1 Synthesis of lipids I and II by VanNieuwenhze et al. Bn, benzyl CDI, l,l -carbonyldiimidazole DBU, l,8-diazabicyclo[5.4.0]undec-7-ene DIPEA, diisopropylethyl-amine EDC, l-ethyl-3-(3-dimethylaminopropyl)carbodiimide NHS, A-hydroxysuccinimide Pyr, pyridine TFA, trifluoroacetyl Troc, 2,2,2-trichloroethoxycarbonyl. 

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