Syn stereochemistry, in catalytic hydrogenation

Syn stereochemistry in catalytic hydrogenation. A solid heterogeneous catalyst adds two hydrogen atoms to the same face of the pi bond (syn stereochemistry). 

The catalytic hydrogenation of alkynes is similar to the hydrogenation of alkenes, and both proceed with syn stereochemistry. In catalytic hydrogenation, the face of a pi bond contacts the solid catalyst, and the catalyst weakens the pi bond, allowing two hydrogen atoms to add (Figure 9-2). This simultaneous (or nearly simultaneous) addition of two hydrogen atoms on the same face of the alkyne ensures syn stereochemistry. 

---

See also in sourсe #XX -- [ ]

---